5X7 Vintage matte finish photograph signed in fountain pen ink, "P. Debye, 3.5.57." In excellent condition.(1884-1966) Peter Joseph William Debye was a Dutch-American physicist physical chemist, and Nobel laureate in Chemistry in 1936.His first major scientific contribution was the application of the concept of dipole moment to the charge distribution in asymmetric molecules in 1912, developing equations relating dipole moments to temperature and dielectric constant. In consequence, the units of molecular dipole moments are termed debyes in his honor. Also in 1912, he extended Albert Einstein's theory of specific heat to lower temperatures by including contributions from low-frequency phonons. See Debye model.In 1913, he extended Niels Bohr's theory of atomic structure, introducing elliptical orbits, a concept also introduced by Arnold Sommerfeld. In 1914–1915, Debye calculated the effect of temperature on X-ray diffraction patterns of crystalline solids with Paul Scherrer (the "Debye–Waller factor"). In 1923, together with his assistant Erich Hückel, he developed an improvement of Svante Arrhenius' theory of electrical conductivity in electrolyte solutions. Although an improvement was made to the Debye–Hückel equation in 1926 by Lars Onsager, the theory is still regarded as a major forward step in our understanding of electrolytic solutions. Also in 1923, Debye developed a theory to explain the Compton effect, the shifting of the frequency of X-rays when they interact with electrons.In a 2010 publication, Jurrie Reiding asserts that Debye may have been an MI6 spy.Reiding discovered that Debye was befriended by the well-documented spy Paul Rosbaud. They first met around 1930 when they were both working as editors for two scientific journals. They collaborated in the escape of Lise Meitner in 1938. According to Reiding, Debye was well-connected in German scientific and industrial circles and could have provided MI6 with valuable information. For example, as board member of the German Academy for Aviation Research he was acquainted with Hermann Göring. Reiding also offers an explanation for Debye's hasty departure on 16 January 1940 for the United States: the date coincided with the planned (but later delayed) German invasion of the Netherlands a day later, information possibly provided to him by Rosbaud.This lot came from the Jim Wiggins collection we purchased in July 2022. Jim Wiggins accumulated the most unique and valuable autograph collection over a period of 70-plus years. He obtained his collection either in person or by writing to persons of fame and notoriety. Comes with a full Letter of Authenticity from Todd Mueller Authentics.